Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics

نویسندگان

  • Nuria García
  • Patricia García-García
  • Manuel A. Fernández-Rodríguez
  • Rubén Rubio
  • María R. Pedrosa
  • Francisco J. Arnáiz
  • Roberto Sanz
چکیده

Pinacol is described as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups have been efficiently and selectively reduced being acetone and water the only byproducts of these reactions.

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تاریخ انتشار 2011